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Exploring transport properties of engineered nanotube membranes

Research Area: Physics, nanofluidics, separation and membrane science and nanotube membranes

Degree: Honours

Supervisor: Dr Mihail Popescu

Description: Nanofluidics is often defined as the study and application of fluid flow in and around nanosized objects. There are many research disciplines related to nanofluidics and application of nanofluidics in separation and membrane science is one of a particularly growing research area. Separation using membranes is currently seen as one of the most promising and cost effective separation strategies. However advances are needed in the development of new membranes and separation approaches using novel and more effective nanoporous materials. Intensive research over past years is directed toward the exploring different nanoporous materials for membrane applications. Among them nanotube (nanochannel) membranes which consist of ordered arrays of vertically aligned cylindrical channels with sizes of few to tens nm are a particularly promising. In comparison with other porous membranes, the advantages of nanotube membranes are their low fabrication cost, the ability to control channel dimensions (diameter, length), the flexibility in using different materials (gold, silica, carbon), the ability to use a wide range of surface modifications and functionalisations, and the flexibility in applying a variety of selectivity approaches. If these membranes are to be used for real-world practical separations, strategies to increase their low transport rate and improve their selectivity need to be further developed.

The aim of the project is to theoretically address, in close connection with the experimental work, the transport properties of nanotube membranes with a view on optimizing their transport and selectivity properties. Specifically, this research proposed to study the influence of the size and the shape (eg., conical and asymmetrically modulated) of the engineered nanotube membranes on the transport properties.

The student is expected to combine theoretical modeling with numerical methods and/or numerical simulations, thus a background in physics, engineering or applied mathematics is required, and there will be opportunities for collaboration with other research groups at The Wark.

References
1. K.B. Jirage, J.C. Hulteen, C.R. Martin, Nanotube-Based Molecular-Filtration
Membranes, Science 278, 655-658 (1997).
2. K. B. Jirage, C.R. Martin, Trends Biotechnol. 17, 197 (1999).
3. C. Kettner, P. Reimann, P. Hanggi, F. Muller, Phys. Rev. E. 61, 312 (2000).

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