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Liquid crystal wetting properties for novel microfluidic sensors

Research Area: Physics, chemistry, surface engineering, soft matter

Supervisors: Dr Craig Priest, Dr Martin Brinkmann* and Stephan Herminghaus* (*Max-Planck Institute for Dynamics and Self-Organization, Germany)

Description: Liquid crystals are well-known for their use in LCD devices (especially flat screen displays), however they have significant potential for use as powerful, autonomous sensors for harmful chemicals or biological agents. The optical response observed on LCD televisions is due to the crystal-like alignment of LC molecules, induced by surface properties within the screen that can be switched by external electrical fields. While many devices contain LCs as flat confined films, supporting these films in open surface structures has the potential to realise microfluidic sensors for a range of chemical and biological species in liquid systems. However, several fundamental challenges exist. The stability of these supported films will depend on their wetting properties (capillarity), which may be influenced by the molecular alignment itself.

This project will reveal how the internal crystal-like properties of LCs influence how they spread over various surface geometries. The knowledge developed during the course of this project will inform the development of novel microfluidic sensors that are highly-sensitive, portable, and require no power to operate.

Techniques
Photolithography
Wet and Deep Reactive Ion Etching
Polarisation microscopy
Atomic Force Microscopy
Wettability measurements
Microfluidics

References
1. Forsberg, P. S. H.; Priest, C.; Brinkmann, M.; Sedev, R.; Ralston, J., Langmuir 2010, 26, 860.
2. Priest, C.; Albrecht, T. W. J.; Sedev, R.; Ralston, J., Langmuir 2009, 25, 5655.
3. Priest, C.; Sedev, R.; Ralston, J., Physical Review Letters, 2007, 99, 026103.
4. Guo, W.; Herminghaus, S.; Bahr, C., Langmuir 2008, 24, 8174-8180
5. Cadwell, K. D.; Lockwood, N. A.; Nellis, B. A.; Alf, M. E.; Willis, C. R.; Abbott, N. L., Sensors and Actuators B: Chemical 2007, 128, 91-98.

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