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Increasing composite particle recovery by optimizing the flotation medium characteristics

Research Area: Chemical engineering, mineral processing, mineralogy

Supervisors: A/Prof Daniel Fornasiero and Dr Max Zanin

Description: Value minerals locked in composite particles in coarse size fractions is the single largest contribution to value mineral loss from many base metal sulfide flotation plants. The coarse particle flotation rate is controlled by detachment of particles from bubbles, which in turn is dependent upon particle hydrophobicity and flotation cell turbulence. For composite particles, containing regions of hydrophobic value and less hydrophobic gangue, the bubble may attach to the hydrophobic region of high contact angle but the expansion of the three phase line of contact is limited due to the presence of hydrophilic regions. Hence, the equilibrium contact angle may never be achieved, and the force of attachment is decreased relative to that possible for homogenous particles containing only the hydrophobic value mineral. Studies within the P260E project have revealed that dramatic increases in the recovery of homogeneous coarse particles can be achieved by simply increasing the medium viscosity. This project will further explore the influence of the separating medium (viscosity, specific gravity) on the detachment of composite particles from bubbles.

The project objective will be to investigate the conditions for detachment of model composite particles from bubbles under controlled turbulent and pulp rheological conditions, in particular pulp density.

Expected outcomes: To determine the critical hydrophobicity of composite coarse particles (including % liberation, distribution and size of each phase) for a specific size fraction to be floated for a given power input under different pulp rheological conditions. The flotation characteristics of synthesis composite particles, eg, lead borate - silica composite, will be investigated after altering the medium specific gravity by adjusting either % solids of suspended particles (ferrosilicon), and/or medium viscosity by addition of viscosity modifiers.

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